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Bibliografická citace

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Hoboken : John Wiley & Sons, c2003
xii,388 s. : il.

objednat
ISBN 0-471-07935-9 (váz.)
Obsahuje ilustrace, tabulky, grafy, bibliografické citace, předmluvu, úvod, rejstřík, údaje o autorech
Nanotechnologie - pojednání
000041375
Preface xi // 1 Introduction 1 // 2 Introduction to Physics of the Solid State 8 // 2.1 Structure 8 // 2.1.1 Size Dependence of Properties 8 // 2.1.2 Crystal Structures 9 // 2.1.3 Face-Centered Cubic Nanoparticles 12 // 2.1.4 Tetrahedrally Bonded Semiconductor Structures 15 // 2.1.5 Lattice Vibrations 18 // 2.2 Energy Bands 20 // 2.2.1 Insulators, Semiconductors, and Conductors 20 // 2.2.2 Reciprocal Space 22 // 2.2.3 Energy Bonds and Gaps of Semiconductors 23 // 2.2.4 Effective Masses 28 // 2.2.5 Fermi Surfaces 29 // 2.3 Localized Particles 30 // 2.3.1 Donors, Acceptors, and Deep Traps 30 // 2.3.2 Mobility 31 // 2.3.3 Excitons 32 // 3 Methods of Measuring Properties 35 // 3.1 Introduction 35 // 3.2 Structure 36 // 3.2.1 Atomic Structures 36 // 3.2.2 Crystallography 37 // 3.2.3 Particle Size Determination 42 // 3.2.4 Surface Structure 45 // 3.3 Microscopy 46 // 3.3.1 Transmission Electron Microscopy 46 // 3.3.2 Field Ion Microscopy 51 // 3.3.3 Scanning Microscopy 51 // 3.4 Spectroscopy 58 // 3.4.1 Infrared and Raman Spectroscopy 58 // 3.4.2 Photoemission and X-Ray Spectroscopy 62 // 3.4.3 Magnetic Resonance 68 // 4 Properties of Individual Nanoparticles // 4.1 Introduction 72 // 4.2 Metal Nanoclusters 74 // 4.2.1 Magic Numbers 74 // 4.2.2 Theoretical Modeling of Nanoparticles 75 // 4.2.3 Geometric Structure 78 // 4.2.4 Electronic Structure 81 // 4.2.5 Reactivity 83 // 4.2.6 Fluctuations 86 // 4.2.7 Magnetic Clusters 86 // 4.2.8 Bulk to Nanotransition 88 // 4.3 Semiconducting Nanoparticles 90 // 4.3.1 Optical Properties 90 // 4.3.2 Photofragmentation 92 // 4.3.3 Coulombic Explosion 93 // 4.4 Rare Gas and Molecular Clusters 94 // 4.4.1 Inert-Gas Clusters 94 // 4.4.2 Superfluid Clusters 95 // 4.4.3 Molecular Clusters 96 // 4.5 Methods of Synthesis 97 // 4.5.1 RF Plasma 97 // 4.5.2 Chemical Methods 98 // 4.5.3 Thermolysis 99 // 4.5.4 Pulsed Laser Methods 100 // 4.6 Conclusion 101 //
5 Carbon Nanostructures // 5.1 Introduction 103 // 72 // 5.2 Carbon Molecules 103 // 5.2.1 Nature of the Carbon Bond 103 // 5.2.2 New Carbon Structures 105 // 5.3 Carbon Clusters 106 // 5.3.1 Small Carbon Clusters 106 // 5.3.2 Discovery of ...107 // 5.3.3 Structure of ... and Its Crystal 110 // 5.3.4 Alkali-Doped ... 110 // 5.3.5 Superconductivity in ... 112 // 5.3.6 Larger and Smaller Fullerenes 113 // 5.3.7 Other Buckyballs 113 // 5.4 Carbon Nanotubes 114 // 5.4.1 Fabrication 114 // 5.4.2 Structure 117 // 5.4.3 Electrical Properties 118 // 5.4.4 Vibrational Properties 122 // 5.4.5 Mechanical Properties 123 // 5.5 Applications of Carbon Nanotubes 125 // 5.5.1 Field Emission and Shielding 125 // 5.5.2 Computers 126 // 5.5.3 Fuel Cells 127 // 5.5.4 Chemical Sensors 128 // 5.5.5 Catalysis 129 // 5.5.6 Mechanical Reinforcement 130 // 6 Bulk Nanostructured Materials 133 // 6.1 Solid Disordered Nanostructures 133 // 6.1.1 Methods of Synthesis 13 3 // 6.1.2 Failure Mechanisms of Conventional Grain-Sized Materials 137 // 6.1.3 Mechanical Properties 139 // 6.1.4 Nanostructured Multilayers 141 // 6.1.5 Electrical Properties 142 // 6.1.6 Other Properties 147 // 6.1.7 Metal Nanocluster Composite Glasses 148 // 6.1.8 Porous Silicon 150 // 6.2 Nanostructured Crystals 153 // 6.2.1 Natural Nanocrystals 153 // 6.2.2 Computational Prediction of Cluster Lattices 153 // 6.2.3 Arrays of Nanoparticles in Zeolites 154 // 6.2.4 Crystals of Metal Nanoparticles 157 // 6.2.5 Nanoparticle Lattices in Colloidal Suspensions 158 // 6.2.6 Photonic Crystals 159 // 7 Nanostructured Ferromagnetism // 7.1 Basics of Ferromagnetism 165 // 7.2 Effect of Bulk Nanostructuring of Magnetic Properties 170 // 7.3 Dynamics of Nanomagnets 172 // 7.4 Nanopore Containment of Magnetic Particles 176 // 7.5 Nanocarbon Ferromagnets 177 // 7.6 Giant and Colossal Magnetoresistance 181 // 7.7 Ferrofluids 186 //
8 Optical and Vibrational Spectroscopy // 8.1 Introduction 194 // 8.2 Infrared Frequency Range 196 // 8.2.1 Spectroscopy of Semiconductors; Excitons 196 // 8.2.2 Infrared Surface Spectroscopy 198 // 8.2.3 Raman Spectroscopy 203 // 8.2.4 Brillouin Spectroscopy 210 // 8.3 Luminescence 213 // 8.3.1 Photoluminescence 213 // 8.3.2 Surface States 215 // 8.3.3 Thermoluminescence 221 // 8.4 Nanostructures in Zeolite Cages 222 // 9 Quantum Wells, Wires, and Dots // 9.1 Introduction 226 // 9.2 Preparation of Quantum Nanostructures 227 // 9.3 Size and Dimensionality Effects 231 // 9.3.1 Size Effects 231 // 9.3.2 Conduction Electrons and Dimensionality 233 // 9.3.3 Fermi Gas and Density of States 234 // 9.3.4 Potential Wells 236 // 9.3.5 Partial Confinement 241 // 9.3.6 Properties Dependent on Density of States 242 // CONTENTS ІХ // 9.4 Excitons 244 // 9.5 Single-Electron Tunneling 245 // 9.6 Applications 248 // 9.6.1 Infrared Detectors 248 // 9.6.2 Quantum Dot Lasers 251 // 9.7 Superconductivity 253 // 10 Self-Assembly and Catalysis 257 // 10.1 Self-Assembly 257 // 10.1.1 Process of Self-Assembly 257 // 10.1.2 Semiconductor Islands 258 // 10.1.3 Monolayers 260 // 10.2 Catalysis 264 // 10.2.1 Nature of Catalysis 264 // 10.2.2 Surface Area of Nanoparticles 264 // 10.2.3 Porous Materials 268 // 10.2.4 Pillared Clays 273 // 10.2.5 Colloids 277 // 11 Organic Compounds and Polymers 281 // 11.1 Introduction 281 // 11.2 Forming and Characterizing Polymers 283 // 11.2.1 Polymerization 283 // 11.2.2 Sizes of Polymers 284 // 11.3 Nanocrystals 285 // 11.3.1 Condensed Ring Types 285 // 11.3.2 Polydiacetylene Types 289 // 11.4 Polymers 292 // 11.4.1 Conductive Polymers 292 // 11.4.2 Block Copolymers 293 // 11.5 Supramolecular Structures 295 // 11.5.1 Transition-Metal-Mediated Types 295 // 11.5.2 Dendritic Molecules 296 // 11.5.3 Supramolecular Dendrimers 302 //
11.5.4 Micelles 305 // 12 Biological Materials 310 // 12.1 Introduction 310 // 12.2 Biological Building Blocks 311 // 12.2.1 Sizes of Building Blocks and Nanostructures 311 // 12.2.2 Polypeptide Nanowire and Protein Nanoparticle 314 // 12.3 Nucleic Acids 316 // 12.3.1 DNA Double Nanowire 316 // 12.3.2 Genetic Code and Protein Synthesis 322 // 12.4 Biological Nanostructures 324 // 12.4.1 Examples of Proteins 324 // 12.4.2 Micelles and Vesicles 326 // 12.4.3 Multilayer Films 329 // 13 Nanomachines and Nanodevices 332 // 13.1 Microelectromechanical Systems (MEMSs) 332 // 13.2 Nanoelectromechanical Systems (NEMSs) 335 // 13.2.1 Fabrication 335 // 13.2.2 Nanodevices and Nanomachines 339 // 13.3 Molecular and Supramolecular Switches 345 // A Formulas for Dimensionality 357 // A. 1 Introduction 357 A.2 Delocalization 357 A.3 Partial Confinement 358 // B Tabulations ol Semiconducting Material Properties 361 // Index 371

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