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BK

Second edition

Amsterdam : Elsevier, Butterworth-Heinemann, 2014

xi, 539 stran : ilustrace ; 24 cm

ISBN 978-0-12-800858-4 (vázáno)

Obsahuje bibliografické odkazy a rejstřík

001470981

Contents // Preface...ix // Acknowledgments...xi // CHAPTER 1 Introduction...1 // 1.1 Carbon materials...1 // 1.2 Short history of carbon materials...4 // 1.3 Classic carbons, new carbons, and nanocarbons...5 // 1.3.1 Classic carbons...5 // 1.3.2 New carbons...6 // 1.3.3 Nanocarbons...10 // 1.4 Construction and purposes of the present book...13 // References...14 // CHAPTER 2 Fundamental Science of Carbon Materials...17 // 2.1 Carbon families...17 // 2.1.1 Carbon—carbon bonds...17 // 2.1.2 Carbon families...17 // 2.1.3 Structural relation to neighboring atoms...22 // 2.2 Structure and texture of carbon materials...25 // 2.2.1 Structure...25 // 2.2.2 Structure development with heat treatment // (carbonization and graphitization)...28 // 2.2.3 Nanotexture... 31 // 2.2.4 Microtexture (agglomeration)...35 // 2.3 Carbonization (nanotexture development)...35 // 2.3.1 Formation processes of carbon materials...35 // 2.3.2 Gas phase carbonization...37 // 2.3.3 Solid phase carbonization...51 // 2.3.4 Liquid phase carbonization...62 // 2.4 Novel techniques for carbonization...72 // 2.4.1 Template method...72 // 2.4.2 Polymer blend method...77 // 2.4.3 Electrospinning...79 // 2.4.4 Pressure carbonization...82 // 2.4.5 High-yield carbonization...86 // 2.4.6 Low-temperature carbonization...90 // 2.5 Graphitization (structure development)...92 // 2.5.1 Structure parameters...92 // 2.5.2 Graphitization behavior...100 // 2.5.3 Relations among structure parameters...121 // VI // Contents // 2.5.4

Graphitization process...126 // 2.5.5 Graphitizing and non-graphitizing carbons...131 // 2.5.6 Heterogeneous graphitization // (multiphase graphitization)...133 // 2.6 Acceleration of graphitization...136 // 2.6.1 Catalytic graphitization...136 // 2.6.2 Stress graphitization...140 // 2.6.3 Graphitization of exfoliated carbon fibers...146 // 2.7 Pore development in carbon materials...148 // 2.7.1 Pores in carbon materials...148 // 2.7.2 Identification of pores...151 // 2.7.3 Pore development in carbon materials...163 // 2.8 Introduction of foreign species...175 // 2.8.1 Possibility to introduce foreign species into // carbon materials...175 // 2.8.2 Intercalation...176 // 2.8.3 Substitution...191 // 2.8.4 Doping...197 // 2.8.5 Dispersion of fine metal particles...201 // References...205 // CHAPTER 3 Engineering and Applications of Carbon // Materials...219 // 3.1 Polycrystalline graphite blocks...219 // 3.1.1 Production...219 // 3.1.2 Applications...225 // 3.1.3 Filler cokes and binder pitches...234 // 3.1.4 Properties...242 // 3.2 Highly oriented graphite...252 // 3.2.1 Highly oriented graphite...252 // 3.2.2 Natural graphite...252 // 3.2.3 Kish graphite...258 // 3.2.4 Highly oriented pyrolytic graphite (HOPG)...263 // 3.2.5 Graphite films derived from polyimide films...266 // 3.2.6 Flexible graphite sheets...278 // 3.3 Non-graphitizing and glass-like carbons...286 // 3.3.1 Structural characteristics...286 // 3.3.2 Properties...291 // 3.3.3 Glass-like carbons...295 // 3.4 Carbon

fibers...298 // 3.4.1 Classification of fibrous carbons...298 // 3.4.2 Characteristics of carbon fibers...300 // 3.4.3 PAN-based carbon fibers...306 // Contents // VII // 3.4.4 Pitch-based carbon fibers...311 // 3.4.5 Vapor-grown carbon fibers...317 // 3.4.6 Glass-like carbon fibers...327 // 3.4.7 Carbon microcoils...329 // 3.5 Nanocarbons...330 // 3.5.1 Carbon nanotubes and nanofibers...330 // 3.5.2 Fullerenes...342 // 3.5.3 Graphene and its derivatives...348 // 3.5.4 Graphyne and graphdiyne...357 // 3.5.5 Single-wall carbon nanohoms...360 // 3.5.6 Helical carbon films...362 // 3.6 Porous carbons...364 // 3.6.1 Activated carbons...364 // 3.6.2 Novel techniques to control pore structure...370 // 3.6.3 Carbon foams (macroporous carbons)...385 // 3.7 Carbon-based composites...389 // 3.7.1 Carbon-based composites...389 // 3.7.2 Carbon/carbon composites...390 // 3.7.3 Carbon/plastics composites...400 // 3.7.4 Carbon/ceramics composites...404 // 3.7.5 Carbon/metal composites...415 // 3.8 Intercalation compounds...416 // 3.8.1 Possible applications...416 // 3.8.2 High conductivity function...418 // 3.8.3 Electrochemical functions...422 // 3.8.4 Catalytic functions...428 // 3.8.5 Gas adsorption and storage...431 // 3.8.6 Other functions...435 // 3.9 Carbon materials for energy storage...438 // 3.9.1 Rechargeable batteries...438 // 3.9.2 Electrochemical capacitors...446 // 3.9.3 Storage of hydrogen gas...462 // 3.9.4 Storage of methane gas...468 // 3.10 Carbon materials for environment

remediation...472 // 3.10.1 Carbon/anatase composites...472 // 3.10.2 Carbon materials for sorption of viscous fluids...483 // 3.10.3 Carbon fibers for environment remediation...500 // References...505 // Index...527 // *

(OCoLC)883459715